Structural and optical properties of mg and cd doped zno. Highly responsive uv light sensors using mgdoped zno. Pdf structural and magnetic properties of almg codoped. Structural and optical properties of post annealed mg doped zno. This paper reports the growth and characterization of transparent magnesium doped zinc oxide. Mgdoped zno nanoparticles were synthesized by planetary ball milling at a speed of 400 rpm and milled for 20 h. Pdf structural and optical properties of mgdoped zno. The bet shows that the surface area of synthesized catalyst increases when the weight ratio of manganese increases up to 1% mn, but decreases thereafter.
Therefore the offcentred distortion and the formation of additional vo bonds will result in the improvement in ferroelectric nature after v incorporation. Zno and mg doped zno nanoparticles with different doping concentration were prepared by precipitation method. Navaneetha pandiyaraj 4 c the crystalline size and lattice parameter of pure and sr doped zno nanoparticles are noted. Structural and optical properties of post annealed mg doped zno thin films deposited by the sol gel method. Bhatti 1 center for micro and nano devices cmnd, department of physics, comsats institute of information technology. Mg doped zno dilute magnetic oxides prepared by chemical method. Structural and magnetic properties of almg codoped nano zno article pdf available in journal of superconductivity and novel magnetism on line 02 april 2011 november 20 with 147 reads. Pdf mg doped zno nanoparticles were synthesized by a simple chemical method at low temperature with mg. Physical and electrical characterization of mgdoped zno. Sep 30, 2016 read electrodeposition of mg doped zno thin film for the window layer of cigs solar cell, applied surface science on deepdyve, the largest online rental service for scholarly research with thousands of academic publications available at your fingertips. Second, for the dilute magnetic semiconducting compounds, there appears to be a correlation of curie temperature with semiconductor bandgap. From figures 24 one may conclude that the zno and mgo nanomicrostructures coexist in the film matrices from the fact that the two xrd pattern in these figures reflects the two o. The optical band gap energy of undoped and mg doped zno thin films was. Apr 22, 2017 undoped and mgdoped zno thin film with various mg concentrations 0.
The semiconducting material is used as the window material in photovoltaic solar cell. Structural, morphological and optical properties of films were investigated by using xray diffraction xrd, field emission scanning. Firstprinciples investigation on the optoelectronic. Optical and piezoelectric properties of mndoped zno films. Zinc oxide zno and doped zno thin films are great interest because of their potential in many technological applications such as display materials, light emitting diodes led, gas sensor, solar cell, laser system, etc. Recent advances and novel approaches of ptype doping of zinc oxide 27 high crystalline quality zno films are successfully deposited using a number of growth platforms, including molecular beam epitaxy mbe, chemical vapor deposition cvd, pulsed laser deposition pld, and reactive sputtering. Agnps decorated mgdoped zno heterostructure with dramatic. Pdf optical properties and enhanced photocatalytic activity. Files available from the acs website may be downloaded for personal use only. Supplementary information pdf 341k article information. Structural and optical characterization of magnesium doped zinc oxide thin. Structural and physical properties of mg doped zinc oxide mzo thin films have been investigated. Influence of mg content on tailoring optical bandgap of mg doped zno thin film prepared by solgel method. In this research, a facile coprecipitation method was used to synthesize pure and mgdoped zno nanoparticles nps.
Pdf mgdoped zno nanoparticles were synthesized by planetary ball milling at a speed of 400 rpm and. The optical properties of the thin films were estimated using the transmission spectrum in the range of 2001100 nm. The structural data obtained from xrd pattern of pure and cu doped zno nanomaterial is tabulated in the table 1. The precursors used were h2o, diethylzinc and bisethylcyclopentadienylmagnesium mg, where the cycle ratio between the zn and mg precursors was varied to alter the mg composition. Additionally, we investigated the biomedical sensing properties of mg doped zno mzo sensing film with regard to urea, creatinine, and glucose solutions and found that the mg doped zno mzo sensing film treated with nh3 plasma for 3 min had the best properties for sensing urea, creatinine, and glucose.
Download fulltext pdf download fulltext pdf mg doped zno films prepared by chemical bath deposition article pdf available in journal of materials science 537. Characterization of mg doped zno nanocrystallites prepared. The increase of optical band gap energy with mg or sn doping may be attributed to electrons generated by oxygen vacancies it is termed as mossburstein effect 9. Mgdoped zno nanoparticle films as the interlayer between. In this work, a promising photocatalyst was prepared and investigated for the photocatalytic degradation of caffeine as a model pharmaceutical pollutant. Development of znobased thin film transistors and phosphorus. Magnesium doped zinc oxide mgzo is one of the potential optical materials in enhancement of the band gap in solid state lighting. J mater sci mgdoped zno films prepared by chemical bath deposition nina winkler 0 1 stefan edinger 1 wolfgang kautek 0 theodoros dimopoulos 1 0 faculty of chemistry, department of physical chemistry, university of vienna, wahringer stra. This tendency can be caused by incorporation of mg on the growing surface. Nanocrystalline undoped and mg doped zno mg zno nanoparticles with compositional formula mg x zn 1x o x0,1,3,5,7,10 and 12 % were synthesized using solgel process.
The results indicated that increasing the doping from 07. This phenomenon was also reported in the transmittance spectra of mg, ga and al, ga codoped zno films that fabricated by dip coating technique 46,47. Mg doped zno mgzno layers were deposited using ald at 200 oc to a thickness of 50 nm. Synthesis and characterization of ni and cu doped zno. Oxygen vacancies and zinc interstitials were found to be the main reasons for roomtemperature ferromagnetism in the codoped zno nps with the support of the results ob.
Fesem images of a undoped zno b mg doped zno films. Solgel derived mg and ag doped zno thin film on glass. Therefore zno films have been prepared by many groups using various methods. In summary, we have synthesized the v doped zno samples by solid state reaction method and investigated their structural, optical and ferroelectric properties. Facile synthesis of mndoped zno porous nanosheets as anode. Despite research articles published each year on the strategies to improve the optoelectronic properties of zno, the.
Pure and mg doped at 14% zno nanoparticles, obtained by. The electrical and physical characteristics of mgdoped zno sensing. Magnesium doped zinc oxide has attracted attention of researchers worldwide due to its wide range of applications in numerous fields. In raman spectra, the high intensive e 2 high mode observed for 438 cm.
Pdf mgdoped zno films by solgel spin coating method. The effect of mg doping on the crystal structure, morphology and optical properties of the nanoparticles was also investigated. Summary of the device parameters for qdleds with zno. Roomtemperature multiferroic properties in mg doped zno samples are reported wherein mg replaces zn in the zno matrix and retains hexagonal wurtzite structure. There is an intense peak which belong to the reflections from 100 in figure 1a and from 002 plane of zno. A direct quantitative comparison is possible on the basis of the double integral values of the signal depicted in the inset of figure 7. The doped mg ions may only act as a buffer in a form of mgo to alleviate the stress caused by the volume changes during the formation of lithiumzinc alloys. Mgdoped zno films prepared by chemical bath deposition. Mg one of the most promising materials for the photonic devices in the ultraviolet range 1. First we have weighting the starting material according to their molarities in the solution. Sudha 1 1post graduate and research department of physics, government arts college, dharmapuri 2post graduate and research department of physics, arignar anna government arts college, villupuram. Zno and mgdoped zno nanoparticles are located at 297 nm and 290 nm, respectively. Enhanced gas sensing properties of spincoated nadoped zno.
Welldispersed undoped and mgdoped zno nanoparticles with different doping con centrations at various annealing temperatures are synthesized using basic. Aug 11, 2015 solutionbased zno nanorod arrays nras were modified with controlled n doping by an advanced ion implantation method and were subsequently utilized as photoanodes for photoelectrochemical pec. Xrd data are used to study phase purity and crystal structure in different doping concentrations. The manganese mn dopant in the form of anhydrous manganese acetate was used to obtain mn doped zno films. Characterisation and modelling of mg doped zno tfts. From ftir result, the zno stretching was observed at 453 and 448 cm.
Mgdoped zno nanostructures for efficient organic light. Pdf mgdoped zno films prepared by chemical bath deposition. Effect of mg doped zno thin film develpoed by electrodeposition method shashikant rajpal, s. N doping to zno nanorods for photoelectrochemical water. Structural, morphological and optical properties of pure. Download hires image download to mspowerpoint cite this. The peak position of 002 plane for mgdoped zno thin films shifts toward higher angle due to the mg doping. Compared with undoped zno, mgdoped zno samples showed a stronger diffraction peak, indicating that the growth of nanoparticles forming mgdoped zno 1. Pdf surface modified mgdoped zno qds for biological imaging. Journal of chemical and pharmaceutical research, 2012, 44.
Agnps decorated mg doped zno heterostructure with dramatic sers activity for trace detection. Synthesis and characterization of manganese doped zno. Effect of doping and annealing on the physical properties of zno. Pdf characterization of mg doped zno nanocrystallites. This method is a simple, economic and effective method to produce high quality films. Experimental fabrication process of magnesiumdoped zno eis structure sensing membrane. Our goal is to help you understand what a file with a. Experimental fabrication process of magnesium doped zno eis structure sensing membrane. Synthesis and characterization of cudoped zno nanorods. This blue shift is due to the filling of the conduction band of zno with the electrons donated by al donors11,12. Synthesis and characteristics of mg doped zno thin films. Correlation of bandgap and urbach energy with mg content. Pdf undoped and mg doped zno films were deposited on glass substrate by solgel spin coating method. Spray pyrolysis, mg doped zno thin films, band gap energy, xrd.
It is observed a significant change in morphology of the mg doped zno films as mg dopant concentration was increased. So we have used zinc chloride 97% and 3% nickel sulphate and copper chloride. Possibility of roomtemperature multiferroism in mgdoped zno. Investigation of structural, optical and photocatalytic properties of sr doped zno nanoparticles s. For pure zno, the o 1s spectrum could be split into three peaks centered at 532. Conclusions the hexagonal wurtzite mg doped zno nanoparticles that are in the form of zn 1xmg xo x 00.
Robust transparent and conductive gas diffusion multibarrier based on mg and al doped zno as indium tin oxidefree electrodes for organic electronics. The zinio electronic magazine file type, file format description, and mac and windows programs listed on this page have been individually researched and verified by the fileinfo team. Li and mg co doped zinc oxide electron transporting layer for highly efficient quantum dot lightemitting diodes hyomin kim, sinyoung cho, jeonggi kim, hyeonjeong shin and jin jang advanced display research center adrc, department of information display, kyung. Xrd patterns of undoped and iron doped zno thin films o btained u sing p recursor s olution of the molarities of 0. Properties of undoped zno and mg doped zno thin films by sol. For instance, by doping impurities such as mn, cr and co, zno with wavelength could be tuned to visible light region was produced pearton et al. The sizes of the grains are found to be in the range between 400 and 450 nm. Research article highly responsive uv light sensors using. The thickness of the al mg co doped zno thin film increases by increasing the number of dipping, withdrawal speed, and solution density. Previous researchers have also suggested that the mgdoped zno and zn 1. Chloridepassivated mg doped zno nanoparticles for improving. All the films have a hexagonal wurtzite structure with major diffraction peaks along 1 0 0, 0 0 2 and 1 0 1 planes 1, 3, 16, 21.
Mgdoped zno nanoparticles for efficient sunlightdriven. Supporting information chloridepassivated mg doped zno. Mg were synthesized using sol gel method on ntype silicon 111 and undergone annealing treatment at 450 c and 550 c using nitrogen gas for 1 h. Pdf zno thin films with different mg doping contents 0%, 3%, 5%, 8%, 10%. Process optimization and device variation of mgdoped zno. Diffraction peaks denoted here are related to the zno. Regular and mgdoped zno sensing membranes at a thickness of 50 nm were deposited onto the silicon. Influence of mg content on tailoring optical bandgap of mg. Qleds were fabricated by using mg doped zno nanoparticles znmgo nps as an interlayer between the zno electron transport layer and active inp qd layer. Growth of pure and doped zno thin films for solar cell applications m. Structural and optical properties of mg doped zno thin. Li and mg codoped zinc oxide electron transporting layer.
Structural, optical and ferroelectric properties of v doped zno. Absence of ferromagnetism in mn and co doped zno c. Preparation of mgdoped zno nanoparticles by mechanical. The present study reports the observations made on investigations carried out to study structural, optical and electrical properties of aluminium oxide doped zno thin films obtained by thermal. The xrd diffraction peaks match with the pattern of the standard hexagonal structure of zno that reveals the formation of hexagonal wurtzite structure in all samples. The pure and codoped zno nps showed significant changes in the mh loop where the diamagnetic behavior of zno changes to ferromagnetic nature when doping with co. These features may make mg, al co doped zno an excellent transparent conducting electrode for optoelectronic elements. Xray photoelectron spectroscopy xps, uvvis spectroscopy and photoluminescence pl spectroscopy were employed to establish the electronic and optical properties of these nanoparticles. Mgo and zno composite thin films using the spin coating. Zno and mg doped zno nanoparticles are located at 297 nm and 290 nm, respectively. Undoped and mg doped zno thin film with various mg concentrations 0. Influence of mg doping on zno nanoparticles for enhanced. Effect of cobalt doping on structural, optical, and magnetic.
We have doped the ni and cu in the zno both with 3% by weight. Structural, optical and magnetic properties of fe doped zno. Mgdoped zno films prepared by chemical bath deposition pdf. As zno alloys are synthesized, the structural properties are analyzed using xray diffraction xrd and scanningelectron microscopy and. Pdf structural and optical properties of mgdoped zno thin films.
Doped zno nanorods could be synthesized either by ex situ or in situ approach. Pdf optical and electrical properties of sndoped zinc. Apr 16, 2014 read controllable morphology and tunable colors of mg and eu ion co doped zno by thermal annealing, crystengcomm on deepdyve, the largest online rental service for scholarly research with thousands of academic publications available at your fingertips. In this work, solgel sg and hydrothermal ht methods were used separately or in combination in order to obtain zno films doped with mn 1, 2, and 5% for possible application in transparent optoelectronics or as piezoelectric materials. Growth of pure and doped zno thin films for solar cell. Properties of undoped zno and mg doped zno thin films by. Preparation, growth, and optical properties of of almg co.
Structural and optical properties of mg doped zno thin films. A theoretical study, conducted by using dft methods, showed that the improvement in the photocatalytic performance of mg. From the plots, we found that samples annealed at 400. Mg doped zno dilute magnetic oxides prepared by chemical. Undoped and mg doped zno films were deposited on glass substrate by solgel spin coating method.
Pdf sn dopant in zno may significantly improve the ntype conductivity of zno through a characteristic double effect. Mg nps synthesized in the presence of different mg doping contents. Zno based transparent conductive thin films have attracted much attention as a promising substitute material to the currently used indiumtinoxide thin films in transparent electrode applications. Abdul razak nano optoelectronics research laboratory, school of physics, universiti sains malaysia usm, 11800, minden, pulau pinang, malaysia. Pdf preparation of mgdoped zno nanoparticles by mechanical. Smooth, dense and crack free thin film was produced. The following are the supplementary data related to this article. Assessing the potential of mgdoped cr2o3 as a novel ptype. Research article highly responsive uv light sensors using mg doped zno nanoparticles mirzashirjeelalam, 1 umairmanzoor, 1,2 mohammadmujahid, 3 andarshads. In this paper we present further physical characterization of the mg doped zno mgzno films using the photoelectron spectroscopic techniques pes of xray photoelectron spectroscopy xps and inverse photoemission spectroscopy ipes to assess the effect of mg content on the valence and.
Assessing the potential of mg doped cr 2o 3 as a novel ptype transparent conducting oxide aoife b kehoe1, elisabetta arca 2, david o scanlon3,4, igor v shvets and graeme w watson1 1 school of chemistry and crann, trinity college dublin, dublin 2, ireland 2 school of physics and crann, trinity college dublin, dublin 2, ireland. The electrical and physical characteristics of mgdoped zno sensing membrane in eis. Deepak chemistry and physics of materials unit and csir centre of excellence in chemistry, jawaharlal nehru centre for advanced scientific research, jakkur po. Study of zno and mg doped zno nanoparticles by solgel process. Scanning electron microscope sem images revealed that pure and mgdoped zno nps were in the nanoscale regime with hexagonal. Xrd of various mg doped zno using different sputtering power on mg target while keeping the sputtering power of zno target as 400 w. Mg doped zno have considerable interests owing to their unique optical, thermal and structural properties. In an effort to increase the curie temperature to greater than 300 k, the properties of tm doped zn, mg o will also be investigated, as the addition of mg to zno increases the bandgap. Structural and magnetic properties of al mg co doped nano zno article pdf available in journal of superconductivity and novel magnetism on line 02 april 2011 november 20 with 147 reads. Abstract zinc magnesium oxide znmgo is a ternary iivi direct band gap semiconducting material whose band gap varies from 3 to 4 ev. Solgel derived mg and ag doped zno thin film on glass substrate. However the blue shift may be somewhat neutralized by the competing narrowing of the bandgap due to many body effects.
Zno either by narrowing the bandgap or by introducing energy levels in the bandgap of semiconductor materials. Structural and optical properties of mg doped zno thin films prepared by a modified pechini method article pdf available in crystal research and technology 485 may 20 with 1,064 reads. It is also observed that the magnetic properties such as remanence, saturation magnetization and coercivity field found to be decreasing with increase in temperature. This reduction is probably attributed to the dense surface topography table 4. The pure zno and mg doped zno show only a very small resonance signal at this position, supporting the much lower concentration of shallow donor states in these systems. However, the detailed function of the dopants, acting on the electrical and optical properties of zno based transparent conductive thin films, is not clear yet, which has limited the development and.
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